Kunkely, Horst and Vogler, Arnd (2003) Photolysis of naphthol green B in aqueous solution. Photoreduction of Fe(III) induced by ligand-to-metal charge transfer excitation. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 58 (9). pp. 922-924. ISSN 0932-0776
Full text not available from this repository.Abstract
The intense long-wavelength absorption of Naphthol Green B at lambda(max) = 712 nm is assigned to a ligand-to-metal charge transfer (MLCT) transition. LMCT excitation of the complex in aqueous solution leads to the reduction of Fe(III) to Fe(II) with a quantum yield of phi = 1.14 x 10(-3) at lambda(irr) = 577 nm.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; SPECTRA; photochemistry; charge transfer; iron complexes; Naphthol Green B |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 04 Aug 2021 11:30 |
| Last Modified: | 04 Aug 2021 11:30 |
| URI: | https://pred.uni-regensburg.de/id/eprint/38713 |
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