Synthesis, structure and catalytic activity of new chiral nitrogen-containing ligands

Fonseca, Marı́a Hechavarrı́a and Eibler, Ernst and Zabel, Manfred and Koenig, Burkhard (2003) Synthesis, structure and catalytic activity of new chiral nitrogen-containing ligands. INORGANICA CHIMICA ACTA, 352. pp. 136-142. ISSN 0020-1693

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Abstract

The use of nitrogen-containing ligands for asymmetric catalysis has received growing interest in the last years. In this paper we report the synthesis of three new ligands (5c, 5d and 6) and the X-ray structure analysis of 5c and of the copper(II) complex 6-Cu(II)OTf. The catalytic activity of the ligands was tested in standard asymmetric reactions, but in most of the cases only low yields and poor enantioselectivity was obtained. (C) 2003 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: CIRCULAR DICHROISM; SQUARE-PLANAR; COMPLEXES; CYCLOPROPANATION; EPOXIDATION; OLEFINS; Schiff base; tetradentate ligand; asymmetric catalysis
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Depositing User: Dr. Gernot Deinzer
Date Deposited: 04 Aug 2021 12:22
Last Modified: 04 Aug 2021 12:22
URI: https://pred.uni-regensburg.de/id/eprint/38731

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