Fonseca, Marı́a Hechavarrı́a and Eibler, Ernst and Zabel, Manfred and Koenig, Burkhard (2003) Synthesis of novel nitrogen-containing ligands for the enantioselective addition of diethylzinc to aldehydes. TETRAHEDRON-ASYMMETRY, 14 (14). pp. 1989-1994. ISSN 0957-4166
Full text not available from this repository. (Request a copy)Abstract
New nitrogen-containing ligands derived from the (1R,2R)-trans-cyclohexanediamine chiral core unit have been synthesized and fully characterized. Their catalytic activity was tested in the asymmetric addition of diethylzinc to aldehydes leading to the respective secondary alcohols with enantioselectivities of up to 74% ee. (C) 2003 Elsevier Science Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | DISULFONAMIDE-TI(O-ISO-PR)4-DIALKYL ZINC SYSTEM; CATALYTIC ASYMMETRIC ADDITION; AROMATIC-ALDEHYDES; DIALKYLZINCS; COMPLEXES; ALKYLATION; CYCLOPROPANATION; REAGENTS; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 Aug 2021 06:02 |
| Last Modified: | 05 Aug 2021 06:02 |
| URI: | https://pred.uni-regensburg.de/id/eprint/38815 |
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