Kunkely, Horst and Vogler, Arnd (2003) Photoreactivity of tricarbonyl(cyclohexadienyl)iron cation in aqueous solution. Protonation induced by metal-to-ligand charge transfer excitation. INORGANIC CHEMISTRY COMMUNICATIONS, 6 (7). pp. 830-832. ISSN 1387-7003
Full text not available from this repository.Abstract
The complex [(C6H7)Fe(CO)(3)](+) in aqueous solution undergoes a photodecomposition which leads to the formation of cyclohexadiene and Fe2+ with a quantum yield of phi = 0.32 at lambda(irr) = 280 nm. It is suggested that the reactive excited state is of the (Fe-->C6H7) metal-to-ligand charge transfer (MLCT) type. MLCT excitation facilitates an electrophilic addition of a proton at the C6H7 ligand while in the ground state a nucleophilic attack is favoured. (C) 2003 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTOCHEMICAL-REACTIONS; ORGANYL COMPLEXES; OLEFINS; 1,3-CYCLOHEXADIENE; (E)-1,3,5-HEXATRIENE; DIENES; electronic spectra; charge transfer; photochemistry; iron complexes; cyclohexadienyl complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Aug 2021 13:37 |
| Last Modified: | 10 Aug 2021 13:37 |
| URI: | https://pred.uni-regensburg.de/id/eprint/38858 |
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