Eberwein, M. and Schmid, A. and Schmidt, M. and Zabel, Manfred and Burgemeister, T. and Barthel, J. and Kunz, Werner and Gores, Heiner J. (2003) Synthesis and electrochemical properties of some lithium chelatophosphates. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 150 (7). A994-A999. ISSN 0013-4651
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Two new lithium chelatophosphates have been synthesized, purified, and characterized, lithium tris[3,4,5,6-tetrafluor-1,2-benzenediolato(2-)-O,O']-phosphate(1-) and lithium tris[3-fluoro-1,2-benzenediolato(2-)-O,O']-phosphate(1-). A precursor, the corresponding acid of lithium tris[3,4,5,6-tetrafluor-1,2-benzenediolato(2-)-O,O']-phosphate(1-), H+[P(C6F4O2)(3)](-), presumably a super acid, shows a hexacoordinated phosphorous in X-ray analysis, when solvated by two diethyl ether molecules. The anodic oxidation limits of benzenechelatoborates and - phosphates are closely related to the energy of the highest occupied molecular orbital from semiempirical quantum-mechanical calculations with the help of QuantumCache and MOPAC 2002, yielding E-HOMO = -(3.70 +/- 0.26) x E-OX(+8.4 +/- 1.0). (C) 2003 The Electrochemical Society.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | BATTERY ELECTROLYTES; SALTS; CONDUCTIVITY; LIBOB; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Heiner Jakob Gores Chemistry and Pharmacy > Central Analytical Services |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 07 Sep 2021 12:26 |
| Last Modified: | 07 Sep 2021 12:26 |
| URI: | https://pred.uni-regensburg.de/id/eprint/38869 |
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