Papaiconomou, N. and Simonin, J.-P. and Bernard, O. and Kunz, Werner (2003) Description of vapor-liquid equilibria for CO2 in electrolyte solutions using the mean spherical approximation. JOURNAL OF PHYSICAL CHEMISTRY B, 107 (24). pp. 5948-5957. ISSN 1520-6106
Full text not available from this repository.Abstract
The mean spherical approximation is used to describe the vapor pressure over aqueous solutions containing an electrolyte and carbon dioxide. Three electrolytes have been studied: NaOH, NaCl, and acetic acid. A good representation is obtained with a reduced number of parameters as compared to previous models. These parameters account for the concentration and temperature dependence of the solute sizes and the relative permittivity of solution. The numerical values of these physically interpretable parameters are in a reasonable range.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | REAL IONIC-SOLUTIONS; AQUEOUS SODIUM-CHLORIDE; PRIMITIVE MODEL; CARBON-DIOXIDE; ASSOCIATING ELECTROLYTES; THERMODYNAMIC PROPERTIES; ASYMMETRIC ELECTROLYTES; ACTIVITY-COEFFICIENTS; OSMOTIC COEFFICIENTS; TEMPERATURE-RANGE; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 11 Aug 2021 04:53 |
| Last Modified: | 11 Aug 2021 04:53 |
| URI: | https://pred.uni-regensburg.de/id/eprint/38895 |
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