Hering, Thea and Koenig, Burkhard (2016) Photocatalytic activation of N-chloro compounds for the chlorination of arenes. TETRAHEDRON, 72 (48). pp. 7821-7825. ISSN 0040-4020,
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Photoredox catalysis activates N-chloramines and N-chloro-succinimide (NCS) for the electrophilic chlorination of arenes. The photooxidation of the nitrogen atom to a radical cation induces a positive polarization on the chlorine atom, which results in a higher reactivity in electrophilic aromatic chlorination reactions. (C) 2016 Elsevier Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | SELECTIVE AROMATIC CHLORINATION; ORGANIC-SYNTHESIS; ACIDIC-SOLUTION; HALOGENATION; NITROGEN; HALOSUCCINIMIDES; HYDROCARBONS; Photocatalysis; Electron transfer; Electrophilic chlorination |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Apr 2019 12:35 |
| Last Modified: | 10 Apr 2019 12:35 |
| URI: | https://pred.uni-regensburg.de/id/eprint/3894 |
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