Kunkely, Horst and Vogler, Arnd (2003) The reactivity of gold atoms generated by the photolysis of gold azide complexes in acetonitrile. INORGANIC CHEMISTRY COMMUNICATIONS, 6 (5). pp. 553-554. ISSN 1387-7003
Full text not available from this repository.Abstract
The photolysis of gold azide complexes in CH3CN leads to the formation of colloidal gold and [An(I)(CN)(2)](-). The gold atoms which are initially formed do not only agglomerate to colloidal particles but also react with the solvent. It is suggested that CH3CN adds oxidatively to atomic gold and [An(I)(CN)(2)](-) is generated in subsequent reactions. (C) 2003 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | AQUEOUS-SOLUTION; COLLOIDAL GOLD; AU ATOMS; SPECTRA; PHOTOCHEMISTRY; STATE; AG; electronic spectra; photochemistry; gold complexes; gold atoms; gold colloids |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 11 Aug 2021 06:26 |
| Last Modified: | 11 Aug 2021 06:26 |
| URI: | https://pred.uni-regensburg.de/id/eprint/39034 |
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