Bollwein, Tobias and Westerhausen, Matthias and Pfitzner, Arno (2003) Zinc Bis[mu-N,N '-chlorozinc-bis(N-trimethylsilyliniino-diphenylphosphoranyl)-methanediide]: A zinc derivative of a gentinal carbdianion. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 58 (5). pp. 493-495. ISSN 0932-0776
Full text not available from this repository.Abstract
The trinuclear title compound, C74H88Cl2N4P4Si4Zn3, is derived from a geminally substituted carbdianion. The central zinc atom shows a nearly linear coordination geometry with very short Zn-C bond lengths (average 191 pm). The peripheral metal centers of the chlorozinc moieties are chelated by the phosphanimine donors and hence are triply coordinated, thus forming a six-membered CP2N2Zn ring with Zn-N distances of 195 pm (average).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | X-RAY SCATTERING; geminal carbdianions; metathesis reactions; zinc |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 05 Aug 2021 09:43 |
| Last Modified: | 05 Aug 2021 09:43 |
| URI: | https://pred.uni-regensburg.de/id/eprint/39108 |
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