Hoggard, Patrick E. and Gruber, Michael and Vogler, Arnd (2003) The photolysis of iron(III) chloride in chloroform. INORGANICA CHIMICA ACTA, 346. pp. 137-142. ISSN 0020-1693
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In air-saturated solutions, iron(III) chloride functions as a long wavelength sensitizer of the photolysis of chloroform. In the presence of oxygen, irradiation of chloroform solutions of iron(III) chloride at wavelengths above 340 nm leads to the formation of HFeCl4, followed by continued production of HCl and C2O6 as chlorine photodissociates from HFeCl4, while the Fe(II) species formed is reoxidized. When iron(III) chloride is photolyzed in the absence of oxygen, conversion to HFeCl4 and reduction to colloidal FeCl2 occur simultaneously, ending in complete reduction. Both CCl3OO and CCl3OOH appear to participate in the reoxidation of iron(II) chloride. (C) 2002 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTOREDOX CHEMISTRY; PEROXYL RADICALS; RATE CONSTANTS; ONE-ELECTRON; KINETICS; OXIDATION; PHOTOOXIDATION; COMPLEXES; PHOTOCHEMISTRY; ANTIMONY(III); photolysis; iron complexes; chloride complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences 600 Technology > 610 Medical sciences Medicine |
| Divisions: | Medicine > Lehrstuhl für Anästhesiologie Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 17 Aug 2021 13:48 |
| Last Modified: | 17 Aug 2021 13:48 |
| URI: | https://pred.uni-regensburg.de/id/eprint/39188 |
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