Kunkely, Horst and Vogler, Arnd (2003) Optical properties of (3,3 '-dihydroxy-2,2 '-bipyridine) tricarbonyl-rhenium(I) chloride. Absorption and emission spectra. INORGANICA CHIMICA ACTA, 343. pp. 357-360. ISSN 0020-1693
Full text not available from this repository.Abstract
The complex [bipy(OH)(2)]Re(I)(CO)(3)Cl with bipy(OH)(2) = 3,3'-dihydroxy-2,2'-bipyridine has been prepared and characterized by elemental analysis, ESI MS and UV-Vis spectroscopy. The complex shows a yellow emission at lambda(max) = 582 nm which originates from the lowest-energy bipy(OH)(2) intraligand (IL) triplet. The compound undergoes a reversible deprotonation to [(bipyO(2))Re(I)(CO)(3)Cl](2-) which is not luminescent under ambient conditions. (C) 2002 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PROTON-TRANSFER; EXCITED-STATE; COMPLEXES; LUMINESCENCE; electronic spectra; luminescence; rhenium complexes; polypyridine ligands |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Aug 2021 13:17 |
| Last Modified: | 24 Aug 2021 13:17 |
| URI: | https://pred.uni-regensburg.de/id/eprint/39345 |
Actions (login required)
 |
View Item |
