Kunkely, Horst and Vogler, Arnd (2003) Photooxidation of bis(diethyldithiocarbamato)dicarbonyliron(II) in chloroform. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 154 (2-3). pp. 289-291. ISSN 1010-6030
Full text not available from this repository.Abstract
The complex Fe-II (et(2)dtc)(2)(CO)(2) with et(2)dtc(-) (diethyldithiocarbamate) in CHCl3 undergoes a photooxidation to Fe-III (et(2)dtc)(2)Cl with a quantum yield of phi = 0.0015 at lambda(irr) = 366nm. It is suggested that this photoreaction originates from a (Fe-II --> pi* (et(2)dtc(-))) metal-to-ligand charge transfer or ligand-field excited state. (C) 2003 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | SOLVENT-INITIATED PHOTOCHEMISTRY; DITHIOCARBAMATO COMPLEXES; PHOTOLYSIS; CHEMISTRY; electronic spectra; photooxidation; iron complexes; iron-sulfur compounds |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Aug 2021 13:25 |
| Last Modified: | 24 Aug 2021 13:25 |
| URI: | https://pred.uni-regensburg.de/id/eprint/39350 |
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