Kunkely, Horst and Vogler, Arnd (2003) Excited state properties of a copper(I) benzene complex. Emission from a metal-to-ligand charge transfer state. CHEMICAL PHYSICS LETTERS, 368 (1-2). pp. 49-52. ISSN 0009-2614
Full text not available from this repository.Abstract
The solid compound Cu-2(CF3SO3)(2)(C6H6) shows an intense emission at lambda(max) = 518 nm (phi similar to 10(-2), tau = 0.5 mus) which is suggested to originate from a Cu-1 to benzene metal-to-ligand charge transfer (MLCT) triplet. The spin-allowed MLCT transition gives rise to an excitation maximum at lambda = 318 nm which appears also as long-wavelength band at lambda(max) = 315 nm in the absorption spectrum of the complex in solution. (C) 2002 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOTOASSISTED VALENCE ISOMERIZATION; GROUND-STATE; PI-COMPLEXES; PHOTOCHEMISTRY; COORDINATION; NORBORNADIENE; CHEMISTRY; CLUSTERS; D10; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 25 Aug 2021 10:10 |
| Last Modified: | 25 Aug 2021 10:10 |
| URI: | https://pred.uni-regensburg.de/id/eprint/39360 |
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