The sharpless asymmetric aminohydroxylation - Scope and limitation

Nilov, Dmitry and Reiser, Oliver (2002) The sharpless asymmetric aminohydroxylation - Scope and limitation. ADVANCED SYNTHESIS & CATALYSIS, 344 (10). pp. 1169-1173. ISSN 1615-4150

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Abstract

The asymmetric aminohydroxylation (AA) has emerged as a valuable tool in organic synthesis. Recent developments, such as ligandless variants, new nitrogen reagents and new substrates have considerably broadened the utility of the process. Nevertheless, the understanding of the AA, both in terms of mechanism as well as applicability to common synthetic tasks is still limited. This article summarizes the scope and limitation of the AA with special emphasis on recent advances.

Item Type: Article
Uncontrolled Keywords: OSMIUM-CATALYZED DIHYDROXYLATION; HETEROAROMATIC ACRYLATES; SUBSTITUTED STYRENES; OLEFINS; <2+2>-CYCLOADDITION; ENANTIOSELECTIVITY; REGIOSELECTION; VINYLFURAN; REVERSAL; amino alcohol; aminohydroxylation; asymmetric catalysis; dihydroxylation; osmium
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Depositing User: Dr. Gernot Deinzer
Date Deposited: 25 Aug 2021 12:13
Last Modified: 25 Aug 2021 12:13
URI: https://pred.uni-regensburg.de/id/eprint/39580

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