Synthesis of 1,4-oxazepin-7-ones using Baylis-Hillman products as key intermediates

Nilov, Dmitry and Raecker, Reinhard and Reiser, Oliver (2002) Synthesis of 1,4-oxazepin-7-ones using Baylis-Hillman products as key intermediates. SYNTHESIS-STUTTGART (15). pp. 2232-2242. ISSN 0039-7881, 1437-210X

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Abstract

Baylis-Hilman adducts derived from aromatic aldehydes and methyl acrylate can be readily converted to 1,4-oxazepin-7- ones substituted in 2-, 3-, or 4-position by condensation with amino alcohols.

Item Type: Article
Uncontrolled Keywords: DIELS-ALDER REACTIONS; 2-PYRIDYL DERIVATIVES; THERMAL CYCLIZATION; INDOLIZINES; ALKALOIDS; Baylis-Hillman reaction; 1,4-oxazepin-7-ones; amino alcohols; aromatic aldehydes; lactonization; hydrogenation
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Depositing User: Dr. Gernot Deinzer
Date Deposited: 25 Aug 2021 12:34
Last Modified: 25 Aug 2021 12:34
URI: https://pred.uni-regensburg.de/id/eprint/39762

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