Pitsch, Wolfgang and Klein, Michael and Zabel, Manfred and Koenig, Burkhard (2002) Synthesis and structure of a stabilized 10-membered cyclic enediyne. JOURNAL OF ORGANIC CHEMISTRY, 67 (19). pp. 6805-6807. ISSN 0022-3263
Full text not available from this repository.Abstract
The synthesis and structure of an acetal protected 10-membered cyclic enediyne-1,2-diol rac-10 is reported. The conformational constrain of the unsaturated macrocycle by the acetal protection group prevents the thermal cyclization reaction of the endiyne during synthesis and purification.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | BERGMAN CYCLIZATION; CONJUGATED ENEDIYNES; CHEMICAL SYNTHESIS; MOLECULAR DESIGN; DNA CLEAVAGE; DYNEMICIN-A; RING; CYCLOAROMATIZATION; FUNCTIONALITIES; REARRANGEMENT; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König Chemistry and Pharmacy > Central Analytical Services |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 27 Aug 2021 07:47 |
| Last Modified: | 27 Aug 2021 07:47 |
| URI: | https://pred.uni-regensburg.de/id/eprint/39870 |
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