Excited state properties of transition metal phosphine complexes

Vogler, Arnd and Kunkely, Horst (2002) Excited state properties of transition metal phosphine complexes. COORDINATION CHEMISTRY REVIEWS, 230 (1-2). pp. 243-251. ISSN 0010-8545

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Abstract

Phosphine ligands determine the excited state properties of a variety of coordination compounds. Phosphines not only influence metal-centered excited states, but participate directly in charge transfer transitions owing to their electron donating and accepting ability. Moreover, intraligand excited states are accessible if the phosphine carries suitable substituents. This diversity is illustrated by selected examples. The excited state behavior is discussed on the basis of spectral (absorption and emission) and photochemical properties of appropriate phosphine complexes. (C) 2002 Elsevier Science B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: CHARGE-TRANSFER EXCITATION; PHOTOCHEMICAL PROPERTIES; ELECTRONIC ABSORPTION; MCD SPECTRA; PHOTOLUMINESCENCE; SPECTROSCOPY; RHODIUM(I); IRIDIUM(I); EMISSION; ORBITALS; absorption spectra; emission spectra; charge transfer; photochemistry; phosphine complexes
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Depositing User: Petra Gürster
Date Deposited: 09 Jun 2021 09:38
Last Modified: 09 Jun 2021 09:38
URI: https://pred.uni-regensburg.de/id/eprint/40006

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