Kartsev, Valery Nickolaevich and Rodnikova, M. N. and Bartel, I. and Shtykov, Sergei Nikolaevich (2002) The temperature dependence of internal pressure in liquids. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 76 (6). pp. 903-905. ISSN 0036-0244
Full text not available from this repository.Abstract
Internal pressures were calculated for a large variety of liquids in a wide temperature range from abundant experimental data on isothermal compressibility and thermal volumetric expansion coefficients obtained on a unique piesometric unit. The temperature coefficient of internal pressure was shown to be a structural characteristic of liquids. This coefficient was found to be positive for weakly associated liquids whose structure approximated close packing and negative for liquids with a spatial network of H-bonds. The largest negative temperature coefficient of internal pressure was obtained for water, whose spatial network of H-bonds was most perfect.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 26 Oct 2021 06:29 |
| Last Modified: | 26 Oct 2021 06:29 |
| URI: | https://pred.uni-regensburg.de/id/eprint/40226 |
Actions (login required)
 |
View Item |
