Photoluminescence of (quinap)tricarbonylrhenium(I) chloride with quinap=1-(2-diphenylphosphino-1-naphthyl) isoquinoline

Kunkely, Horst and Vogler, Arnd (2002) Photoluminescence of (quinap)tricarbonylrhenium(I) chloride with quinap=1-(2-diphenylphosphino-1-naphthyl) isoquinoline. CHEMICAL PHYSICS LETTERS, 357 (1-2): PII S0009-. pp. 143-146. ISSN 0009-2614

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Abstract

The complex (quinap)Re-I(CO)(3)Cl, with quinap = 1-(2-diphenylphosphino-1-naphthyl)isoquinoline, shows a luminescence at lambda(max) = 582 nm with phi = 0.12 and tau = 1.4 mus in solution (e.g., CH2Cl2) at r.t. It is suggested that this emission originates from a Re-I to quinap metal-to-ligand charge transfer triplet. CD 2002 Published by Elsevier Science B.V.

Item Type: Article
Uncontrolled Keywords: EXCITED-STATE; COMPLEXES; LUMINESCENCE;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Depositing User: Dr. Gernot Deinzer
Date Deposited: 26 Oct 2021 09:59
Last Modified: 26 Oct 2021 09:59
URI: https://pred.uni-regensburg.de/id/eprint/40271

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