Kunkely, Horst and Vogler, Arnd (2002) Photoreactivity of (2,9-dimethyl-1,10-phenanthroline) copper(I) borohydride. INORGANIC CHEMISTRY COMMUNICATIONS, 5 (4): PII S1387-. pp. 239-241. ISSN 1387-7003
Full text not available from this repository. (Request a copy)Abstract
The complex (dmp)Cu-1(BH4) with dmp=2.9-dimethyl-1.10-phenanthroline displays a long-wavelength absorption at 465 nm which is assigned to a BH4 --> dmp ligand-to-ligand charge transfer (LLCT) transition. In the solid state the LLCT state is emissive (lambda(max)= 626 nm), In non-coordinating solvents such as CH2Cl2, CHCl3 or toluene the complex undergoes a photoredox decomposition leading to the generation of metallic copper, At lambda(irr) = 436 nm (dmp)Cu-1(BH4) disappears with phi = 1.2 x 10(-3). (C) 2002 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | METAL-COMPLEXES; CHARGE-TRANSFER; EXCITED-STATES; SOLID-STATE; NANOCLUSTERS; EMISSION; SYSTEMS; LIGANDS; D10; electronic spectra; luminescence; charge transfer; copper complexes; borohydrides; photochemistry |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Nov 2021 13:42 |
| Last Modified: | 02 Nov 2021 13:42 |
| URI: | https://pred.uni-regensburg.de/id/eprint/40419 |
Actions (login required)
 |
View Item |
