Pfisterer, Karin and Korber, Nikolaus (2002) Synthesis and crystal structure of ammonium tetraamminelithium amidotrithiophosphate-ammonia(1/1) (NH4) [Li(NH3)(4)] [P(NH2)S-3] center dot NH3. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 628 (4). pp. 762-764. ISSN 0044-2313
Full text not available from this repository. (Request a copy)Abstract
Colourless crystals of (NH4)[Li(NH3)(4)][P(NH2)S-3].NH3 were prepared by the reduction of P4S10 with a solution of lithium in liquid ammonia. The X-ray structure determination shows them to contain the pseudo-tetrahedral amidotrithiophosphate anion [P(NH2)S-3](2-) (point group Cs), which is the hitherto unknown final member of a series of previously characterized amidothiophosphates. The ammonium ion and the ammonia molecule of solvation form an diamminehydrogen(1+)-ion N2H7+ with a short, nearly linear hydrogen bond of 2.864(3) Angstrom.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; thiophosphate; liquid ammonia; crystal structure; hydrogen bonding |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 03 Nov 2021 10:06 |
| Last Modified: | 03 Nov 2021 10:06 |
| URI: | https://pred.uni-regensburg.de/id/eprint/40457 |
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