Kunkely, Horst and Vogler, Arnd (2002) Electronic spectra of pi-cylopentadienyl(triethyl phosphine) copper(I). Ligand-to-ligand charge transfer. INORGANIC CHEMISTRY COMMUNICATIONS, 5 (2). pp. 112-114. ISSN 1387-7003
Full text not available from this repository. (Request a copy)Abstract
The complex CpCuI(PEt3) with Cp = cyclopentadienyl shows a longest-wavelength absorption at lambda(max) = 350 nm (in n-hexane) which is assigned to a Cp- --> PEt3 ligand-to-ligand charge transfer (LLCT) transition. An analogy to the ylide Cp--P(+)Propyl(3) is drawn which displays the Cp- to phosphonium charge transfer (CT) absorption at lambda(max) = 267 nm (in n-hexane). Solid CpCu(PEt3) exhibits an emission at lambda(max) = 525 nm which is assumed to originate from the LLCT triplet. (C) 2002 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; D10; electronic spcctra; luminescence; charge transfer; copper complexes; cyclopentadienyl complexes; phosphine complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 09 Nov 2021 13:39 |
| Last Modified: | 09 Nov 2021 13:39 |
| URI: | https://pred.uni-regensburg.de/id/eprint/40625 |
Actions (login required)
 |
View Item |
