Electrical conductivity of reverse micelles in supercritical carbon dioxide

Blattner, Christian and Bittner, Juergen and Schmeer, Georg and Kunz, Werner (2002) Electrical conductivity of reverse micelles in supercritical carbon dioxide. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 4 (10). pp. 1921-1927. ISSN 1463-9076

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Abstract

The conductivity of water/ClPFPE-NH4/scCO(2) systems is studied over a wide range of pressures and droplet volume fractions at 35degreesC and at two constant water-to-surfactant molar ratios, W-0 = 10.3 and 18.7, respectively. The results are interpreted according to three different models for low, intermediate and high concentrations of water and surfactant. Information is obtained about a possible bulk-like behaviour of water, about the approximate size of the micelles, about micellar percolation, and about changes of CO2-water droplet interactions with pressure.

Item Type: Article
Uncontrolled Keywords: IN-OIL MICROEMULSIONS; ANGLE NEUTRON-SCATTERING; CHARGE FLUCTUATION MODEL; WATER-IN-CO2 MICROEMULSIONS; TERNARY MICROEMULSIONS; DIELECTRIC-RELAXATION; ORGANIC-SYNTHESIS; WATER; PERCOLATION; VISCOSITY;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Alumni or Retired Professors > Prof. Dr. Georg Schmeer
Depositing User: Dr. Gernot Deinzer
Date Deposited: 17 Nov 2021 16:48
Last Modified: 17 Nov 2021 16:48
URI: https://pred.uni-regensburg.de/id/eprint/40823

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