Schinnerl, Marina and Seitz, Michael and Kaiser, Anja and Reiser, Oliver (2001) New applications of bis(oxazoline) ligands in catalysis: Asymmetric 1,2-and 1,4-addition of ZnR2 to carbonyl compounds. ORGANIC LETTERS, 3 (26). pp. 4259-4262. ISSN 1523-7060
Full text not available from this repository. (Request a copy)Abstract
[GRAPHICS] The enantioselective addition of ZnR2 to aldehydes (1,2) and cyclic enones (1,4) was accomplished using bis(oxazolines) as chiral ligands. The requirement for hydroxymethylene side chains in the ligands strongly suggests that bimetallic catalysts are decisive for high enantiocontrol in these additions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | OXAZOLINE-PHOSPHITE LIGANDS; CONJUGATE ADDITION; ORGANOMETALLIC REAGENTS; COPPER(II) COMPLEXES; ORGANOZINC REAGENTS; CHIRAL CATALYSTS; ENE REACTIONS; DIETHYLZINC; ALDEHYDES; ENONES; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Nov 2021 06:07 |
| Last Modified: | 23 Nov 2021 06:07 |
| URI: | https://pred.uni-regensburg.de/id/eprint/40859 |
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