Kunkely, Horst and Vogler, Arnd (2001) Photoreactivity of hexakis[mu-(acetato-O : O ')]-mu(3)-oxotriruthenium(III) cation. Photoreduction by oxalate. INORGANIC CHEMISTRY COMMUNICATIONS, 4 (12). pp. 689-691. ISSN 1387-7003, 1879-0259
Full text not available from this repository. (Request a copy)Abstract
In the presence of oxalate the trinuclear oxide-bridged complex [(Ru3O)-O-III(acetate)(6)(CH3OH)(3)](+) in methanol undergoes a photoreduction to the Ru-II/Ru-III mixed-valence complex [Ru3O(acetate)(6)(CH3OH)(3)] with phi = 0.01 and 5 x 10(-4) at lambda (irr) = 366 and 546 nm, respectively. It is suggested that the photolysis is initiated by an oxalate to Ru(III) CT state. (C) 2001 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRIRUTHENIUM COMPLEXES; REVERSIBLE MULTISTEP; ION-PAIRS; PHOTOCHEMISTRY; LIGAND; CLUSTERS; electronic spectra; charge transfer; photochemistry; ruthenium complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Nov 2021 06:29 |
| Last Modified: | 24 Nov 2021 06:29 |
| URI: | https://pred.uni-regensburg.de/id/eprint/40902 |
Actions (login required)
 |
View Item |
