Photooxidation of N,N '-bis(3,5-di-tert.-butylsalicylidene)-1,2-diamino hexane-manganese(III) chloride (Jacobsen catalyst) in chloroform

Kunkely, Horst and Vogler, Arnd (2001) Photooxidation of N,N '-bis(3,5-di-tert.-butylsalicylidene)-1,2-diamino hexane-manganese(III) chloride (Jacobsen catalyst) in chloroform. INORGANIC CHEMISTRY COMMUNICATIONS, 4 (12). pp. 692-694. ISSN 1387-7003

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Abstract

Mn-III(J-salen)Cl (Jacobsen catalyst) with J-salen=N,N'-bis(3,5-di-tert.-butylsaticylidene)-1,2-diaminocyclohexane dianion in CHCl3 is photooxidized by the solvent to a Mn-IV(J-salen) complex, presumably Mn-IV(J-salen)Cl-2, with phi = 0.002 at lambda (irr) = 333 nm. (C) 2001 Elsevier Science BN. All rights reserved.

Item Type: Article
Uncontrolled Keywords: PHOTOSYSTEM-II; MANGANESE(III) COMPLEX; COORDINATED WATER; METAL COMPLEXES; SCHIFF-BASE; SALEN; PHOTOSYNTHESIS; PHOTOCHEMISTRY; EPOXIDATION; PHOTOLYSIS; photochemistry; salen complexes; manganese complexes
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Depositing User: Dr. Gernot Deinzer
Date Deposited: 24 Nov 2021 06:37
Last Modified: 24 Nov 2021 06:37
URI: https://pred.uni-regensburg.de/id/eprint/40903

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