Kunkely, Horst and Vogler, Arnd (2001) Photoluminescence of 8-quinolinolatomethylmercury(II). JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 144 (2-3). pp. 69-72. ISSN 1010-6030
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The organometallic complex CH3HII (oxinate) with oxine = 8-quinolinol or 8-hydroxyquinoline shows a longest-wavelength absorption at lambda (max) = 375 nm (epsilon = 1900) and a red phosphorescence at room temperature (lambda (max) = 638 nm, phi = 5 x 10(-3) at lambda (exc) = 420 nm in benzene). The emitting triplet is of the oxinate intraligand type. It follows that the heavy atom effect of mercury is fully transmitted to the oxinate ligand. (C) 2001 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | INTRALIGAND CHARGE-TRANSFER; FLUORESCENT CHEMOSENSOR; STATE PROPERTIES; SENSORS; COMPLEXES; HG(II); PHOTOPHYSICS; EMISSION; SWITCHES; WATER; luminescence; mercury complexes; oxinate complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Nov 2021 10:34 |
| Last Modified: | 24 Nov 2021 10:34 |
| URI: | https://pred.uni-regensburg.de/id/eprint/40944 |
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