Sauer, Juergen and Baeuerlein, Peter and Ebenbeck, Wolfgang and Fuehlhuber, Hans Dieter and Gousetis, Charalampos and Wernthaler, Konrad (2001) A simple route to cis- and trans-bis-sigma-homobenzenes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (21). pp. 3999-4008. ISSN 1434-193X, 1099-0690
Full text not available from this repository. (Request a copy)Abstract
Photolysis of tetracyclic azo compounds 15, readily available from [4+2] cycloaddition between 1,2,4,5-tetrazines and cyclopropenes, gives access to cis- and traps-bis-sigma -homobenzenes 16 and 17. Thermal transformation of the cis isomers 16 affords cis,cis,cis-1,3,6-cyclooctatrienes 18. Kinetic data for these [sigma 2s+sigma 2s+pi 2s] cycloreversions are reported.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | AZOALKANES; TRIQUINACENE; HOMOBENZENES; HOMOAROMATICITY; HYDROCARBONS; azo compounds; aromaticity; photolysis; rearrangements; bis-sigma-homobenzenes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 30 Nov 2021 06:51 |
| Last Modified: | 30 Nov 2021 06:51 |
| URI: | https://pred.uni-regensburg.de/id/eprint/40969 |
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