Kunkely, Horst and Vogler, Arnd (2001) Photoredox reaction of chloromercurioferrocene induced by metal-to-metal charge transfer excitation. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 143 (2-3). pp. 209-211. ISSN 1010-6030
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The electronic spectrum of (C5H5FeC5H4)-C-II-(HgCl)-Cl-II shows a Fe-II to Hg-II metal-to-metal charge transfer (MMCT) absorption at lambda (max) = 300 nm. The photolysis of the complex in ethanol/HClO4 mixtures induced by MMCT excitation leads to the formation of [(C5H5FeC5H5)-C-III](+) and elemental mercury with phi = 7 x 10(-3) at lambda (irr) = 313 nm. @ 2001 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | VALENCE; COMPLEXES; absorption spectra; charge transfer; ferrocene; mercury(II) |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 06 Dec 2021 07:18 |
| Last Modified: | 06 Dec 2021 07:18 |
| URI: | https://pred.uni-regensburg.de/id/eprint/41038 |
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