Synthesis and crystal structure of tricesium undecaphosphide-ammonia(1/3)Cs3P11 center dot 3NH(3)

Knettel, D. and Reil, M. and Korber, Nikolaus (2001) Synthesis and crystal structure of tricesium undecaphosphide-ammonia(1/3)Cs3P11 center dot 3NH(3). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 56 (10). pp. 965-969. ISSN 0932-0776

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Abstract

Cs3P11. 3NH(3) was obtainedfrom asolution of Cs3P11 in liquid ammonia. Its structure consists of P-11(3-)-cage. anions, which coordinate the cesium cations together with ammonia molecules, resulting in a three-dimensional network. The compound completes a family of structures that are derived from the binary phosphide Cs3P11 through the stepwise expanding and dismantling of the three-dimensional network of ions by ammonia molecules of coordination or through the exchange of the cesium cations for voluminous molecular cations.

Item Type: Article
Uncontrolled Keywords: ; polyphosphides; liquid ammonia; tricesium-undecaphosphide-ammonia(1/3) CS3P1I center dot 3 NH3
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Depositing User: Dr. Gernot Deinzer
Date Deposited: 07 Dec 2021 07:16
Last Modified: 07 Dec 2021 07:16
URI: https://pred.uni-regensburg.de/id/eprint/41087

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