Photoreactivity of gold complexes

Vogler, Arnd and Kunkely, Horst (2001) Photoreactivity of gold complexes. COORDINATION CHEMISTRY REVIEWS, 219. pp. 489-507. ISSN 0010-8545

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Abstract

The light sensitivity of gold compounds has been known since 1737. More recent observations have led to a deeper understanding of the photochemistry of gold complexes, which are discussed on the basis of selected examples. Light sensitive Au(I) and Au(III) compounds are classified according to the nature of reactive excited states: metal-centered (MC), ligand-to-metal charge transfer (LMCT), metal-to-ligand charge transfer (MLCT), metal-to-metal charge transfer (MMCT) and intraligand (IL). Accordingly, some basic information on the electronic spectra of gold complexes including luminescence spectra is provided. The photochemistry is described in more detail. Essentially, our own observations are reported but some relevant observations of other groups are also included. (C) 2001 Elsevier Science B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: CHARGE-TRANSFER EXCITATION; RAY CRYSTAL-STRUCTURE; EXCITED-STATE; SPECTROSCOPIC PROPERTIES; PHOSPHINE COMPLEXES; METAL-COMPLEXES; SOLID-STATE; PHOTOCHEMISTRY; LUMINESCENCE; PHOTOOXIDATION; photochemistry; gold complexes; electronic spectra
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Depositing User: Petra Gürster
Date Deposited: 14 May 2021 06:57
Last Modified: 14 May 2021 06:57
URI: https://pred.uni-regensburg.de/id/eprint/41119

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