Bionic catalyst design: A photochemical approach to artificial enzyme function

Knoer, Guenther (2001) Bionic catalyst design: A photochemical approach to artificial enzyme function. CHEMBIOCHEM, 2 (7-8). 593-+. ISSN 1439-4227

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Abstract

To mimic the regulation mechanisms and the selective chemistry of enzymes in the absence of a protein environment, a novel bio-inspired catalyst design strategy is applied with photosensitive coordination compounds acting as photocatalytic artificial enzymes (photozymes). As an example, a robust synthetic oxidoreductase photozyme is described (see reaction scheme; M = Sb) and its efficiency is compared to that of native enzymes and other functional model compounds.

Item Type: Article
Uncontrolled Keywords: GALACTOSE-OXIDASE; RADICAL REACTIONS; OXIDATION; ALCOHOLS; ACTIVATION; OXYGEN; bioinorganic chemistry; enzyme models; homogeneous catalysis; hydrogen transfer; photochemistry
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 14 Dec 2021 06:38
Last Modified: 14 Dec 2021 06:38
URI: https://pred.uni-regensburg.de/id/eprint/41198

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