Moussa, Mehdi Elsayed and Attenberger, Bianca and Fleischmann, Martin and Schreiner, Andrea and Scheer, Manfred (2016) The Diphosphorus Complex [Cp2Mo2(CO)(4)(eta(2)-P-2)] as a Building Block for the Synthesis of Mixed-Hybrid Coordination Polymers. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (28). pp. 4538-4541. ISSN 1434-1948, 1099-0682
Full text not available from this repository. (Request a copy)Abstract
The three-component reaction of the tetrahedral diphosphorus complex [Cp2Mo2(CO)(4)(eta(2)-P-2)] (1), with Ag[BF4] (2) in the presence of 2,2'-bipyrimidine (3) leads to the formation of the two novel two-dimensional networks 4 and 5. Compound 4 is a new two-dimensional organometallic-organic hybrid polymer, while derivative 5 represents a unique two-dimensional organometallic-inorganic-organic hybrid polymer. These results show the possibility of synthesizing a new class of coordination polymers, which could not be obtained from two-component reactions with organic molecules in addition of metal ions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ONE-DIMENSIONAL POLYMERS; STRUCTURAL VARIATION; MAGNETIC-PROPERTIES; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; NMR-SPECTROSCOPY; GAS-ADSORPTION; LIGANDS; CONSTRUCTION; MACROCYCLES; Self-assembly; Phosphorus; Hybrid polymers; 2,2 '-Bipyrimidine; Molybdenum |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 15 Mar 2019 12:06 |
| Last Modified: | 15 Mar 2019 12:06 |
| URI: | https://pred.uni-regensburg.de/id/eprint/4135 |
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