Kunkely, Horst and Vogler, Arnd (2001) Electronic spectra of solid pentakis(dimethylamido)tantalum(V). INORGANIC CHEMISTRY COMMUNICATIONS, 4 (5). pp. 252-253. ISSN 1387-7003
Full text not available from this repository. (Request a copy)Abstract
The electronic spectra of the complex Ta-V(NMe2)(5) are characterized by amide --> Ta(V) ligand-to-metal charge transfer (LMCT) transitions. In the reflectance and excitation spectrum the longest-wavelength LMCT band appears at lambda (max) similar to 415 nm. The emission of Ta(NMe2)(5) which originates from the lowest-energy LMCT triplet occurs at lambda (max) = 578 nm and decays with tau = 0.9 mus at r.t. (C) 2001 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | IMIDO COMPOUNDS; LUMINESCENCE; TANTALUM; electronic spectra; luminescence; tantalum complexes; amido complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 31 Jan 2022 14:55 |
| Last Modified: | 31 Jan 2022 14:55 |
| URI: | https://pred.uni-regensburg.de/id/eprint/41459 |
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