Pitsch, Wolfgang and Russel, Alex and Zabel, Manfred and Koenig, Burkhard (2001) Synthesis of a functionalized cyclohepten-one from erythronic acid-4-lactone. TETRAHEDRON, 57 (12). pp. 2345-2347. ISSN 0040-4020
Full text not available from this repository. (Request a copy)Abstract
A convenient two-step synthesis of a functionalized and chiral cyclohepten-one 4, which may serve as a useful building block in synthesis, is reported. The X-ray structure analysis of the intermediate hemiacetal 2 reveals the presence of a single anomer in the solid state, that equilibrates rapidly in solution. (C) 2001 Elsevier Science Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | FLUORIDE-MEDIATED REACTIONS; SILYL KETENE ACETALS; LACTONES; RINGS; cyclohepten-one; cyclization; TMS |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König Chemistry and Pharmacy > Central Analytical Services |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 08 Feb 2022 15:27 |
| Last Modified: | 08 Feb 2022 15:27 |
| URI: | https://pred.uni-regensburg.de/id/eprint/41635 |
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