Photophysical characterization of diphenyl-substituted phenylenevinylene and diphenylenevinylene polymers

Holzer, W. and Penzkofer, Alfons and Stockmann, R. and Meysel, H. and Liebegott, H. and Hoerhold, H. H. (2001) Photophysical characterization of diphenyl-substituted phenylenevinylene and diphenylenevinylene polymers. POLYMER, 42 (7). pp. 3183-3194. ISSN 0032-3861

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Abstract

Neat films and solutions of poly[1,4-phenylene-1,2-di(4-phenoxyphenyl)vinylene], poly[1,4-phenylene-1,2-di(phenthiophenyl)vinylene], poly[4,4'-diphenylene-1,2-di(4-phenoxyphenyl)vinylene] and poly [4,4'-diphenylene-1,2-di(4-fluorophenyl)vinylene] in 1,4-dioxane are investigated. The optical constants of the neat films are determined, absorption and fluorescence data are analysed, and picosecond laser saturable absorption studies are carried out. The fluorescence lifetimes and fluorescence quantum yields are analysed to determine the emitting chromophore size (electronic delocalization). The saturable absorption measurements are used to determine the average absorption segment size. (C) 2001 Elsevier Science Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: OPTICAL-CONSTANTS MEASUREMENT; WAVE-GUIDES; DPOP-PPV; FLUORESCENCE BEHAVIOR; 2-PHOTON ABSORPTION; CONJUGATED POLYMER; NONRESONANT N(2); THIN-FILMS; 347.15 NM; SINGLE; luminescent polymers; phenylenevinylene polymers; diphenylenevinylene polymers
Subjects: 500 Science > 530 Physics
Divisions: Physics > Institute of Experimental and Applied Physics > Alumni or Retired Professors > Group Alfons Penzkofer
Depositing User: Dr. Gernot Deinzer
Date Deposited: 14 Feb 2022 16:34
Last Modified: 14 Feb 2022 16:34
URI: https://pred.uni-regensburg.de/id/eprint/41732

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