Kunkely, Horst and Vogler, Arnd (2001) Outer-sphere charge-transfer excitation in the ion pair [Co(NH3)(6)](3+)[B12H12](2-). COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 66 (1). pp. 119-124. ISSN 0010-0765, 1212-6950
Full text not available from this repository. (Request a copy)Abstract
The aqueous ion pair [Co(NH3)(6)](3+)[B12H12](2-) displays an UV absorption at lambda (max) = 250 nm which is assigned to an outer-sphere charge-transfer (OSCT) transition from [B12H12](2-) to [Co(NH3)(6)](3+). OSCT excitation leads to photoredox reaction with the formation of Co2+ (Phi = 0.03 at lambda (irr) = 313 nm).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; CLUSTERS; METALLOBORANES; REDUCTION; VERTICES; C2BN-2HN; ANIONS; charge transfer complexes; photochemistry; cobalt(III) complexes; boranates; boranes; UV spectroscopy |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Feb 2022 07:37 |
| Last Modified: | 28 Feb 2022 07:37 |
| URI: | https://pred.uni-regensburg.de/id/eprint/41842 |
Actions (login required)
 |
View Item |
