Vogler, Arnd and Kunkely, Horst (2001) Electronic spectra and photoreactivity of cyclopentadienyl complexes. COORDINATION CHEMISTRY REVIEWS, 211 (1). pp. 223-233. ISSN 0010-8545, 1873-3840
Full text not available from this repository. (Request a copy)Abstract
The cyclopentadienyl (Cp) ligand coordinates to high- and low-oxidation state transition metals as well as main group metals. Consequently, a variety of different excited states and photoreactions is possible, This diversity is illustrated by selected examples. Recent observations are emphasized. Spectral and photochemical properties are related to the following electronic transitions: metal-centered (e.g, Cp2NbCl2, TlCp), intraligand, ligand-to-metal charge transfer (e.g. CpReO3, CpTiCl3, Cp2TiS5, TlCp), metal-to-ligand charge transfer, ligand-to-ligand charge transfer (e.g. Cp2Zr-2,2'-biquinoline(2+)), metal-to-metal charge transfer (e.g. Cp2Ti[NCRu(CN)(5)](2)(6-)), outer sphere charge transfer (e.g. CoCp2+Mn(CO)(5)(-), CpWH2 x 9,10-phenanthrenequinone) and charge-transfer-to-solvent. The Cp ligand may be directly involved in these electronic transitions or act as a spectator ligand. (C) 2001 Elsevier Science B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CHARGE-TRANSFER EXCITATION; MAIN-GROUP ELEMENTS; ARENE REPLACEMENT REACTIONS; COORDINATION-COMPOUNDS; METAL; PHOTOCHEMISTRY; METALLOCENES; FERROCENE; LIGAND; LUMINESCENCE; electronic spectra; photoreactivity; cyclopentadienyl complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Petra Gürster |
| Date Deposited: | 07 May 2021 04:37 |
| Last Modified: | 07 May 2021 04:37 |
| URI: | https://pred.uni-regensburg.de/id/eprint/41845 |
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