Korber, Nikolaus and Richter, Frank (2001) Low-temperature synthesis of diamminesodium(1+) triamminesodium(1+) trithioantimonate (3-) ammoniate (1 : 2 : 1 : 2) ([Na(NH3)(3)](2)[Na(NH3)(2)]SbS3 center dot 2 NH3), a solvated neutral sodium trithioantimonate(3-) (3 : 1) Na3SbS3) ion complex. HELVETICA CHIMICA ACTA, 84 (8). pp. 2368-2372. ISSN 0018-019X
Full text not available from this repository. (Request a copy)Abstract
A solution of sodium in liquid ammonia reacts with Sb2S3 to form large colorless crystals of the composition Na3SbS3. 10 NH3. The trigonal-pyramidal SbS33- anion is ion-paired with three Na+ counter ions, the coordination spheres of which are completed by eight ammine ligands. The resulting neutral [Na(NH3)(3)](2)-[Na(NH3)(2)]SbS3 Molecules crystallize together with two ammonia molecules of solvation in the space group P2(1)/c (a = 9.828(2), b = 6.0702(4), c = 33.4377(6) Angstrom, beta = 91.362(7)degrees, V= 1994.2(5) Angstrom (3), Z = 4).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Feb 2022 14:11 |
| Last Modified: | 28 Feb 2022 14:11 |
| URI: | https://pred.uni-regensburg.de/id/eprint/41865 |
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