Knoer, Guenther (2000) Evidence for the photochemical formation of a high-valent (2)A(2u) antimony porphyrin pi-radical cation. INORGANIC CHEMISTRY COMMUNICATIONS, 3 (10). pp. 505-507. ISSN 1387-7003
Full text not available from this repository. (Request a copy)Abstract
Irradiation of [Sb-V(tpp)(OH)(2)](+) (tpp = dianion of 5,10,15,20-tetraphenylporphyrin) at 298 K in argon saturated dichloromethane under steady state conditions results in the formation of the highly oxidising pi-radical cation [Sb-V(tpp)(OH)(2)](2+) with spectral characteristics corresponding to a (2)A(2u) electronic ground state. (C) 2000 Elsevier Science S.A. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ELECTRON-TRANSFER; HEME ENZYMES; COMPLEXES; OXIDATION; MECHANISM; MODELS; BOND; porphyrins; radical cations; oxidations; photochemistry; enzyme models |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 Mar 2022 15:30 |
| Last Modified: | 22 Mar 2022 15:30 |
| URI: | https://pred.uni-regensburg.de/id/eprint/42170 |
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