Vogler, Arnd (2016) Luminescence of some simple tetracoordinate organoboron complexes in solution. Fluorescence from ligand to ligand CT states. INORGANIC CHEMISTRY COMMUNICATIONS, 72. pp. 83-85. ISSN 1387-7003, 1879-0259
Full text not available from this repository.Abstract
The Lewis base-Lewis acid adducts with the Lewis bases pyrazine, triphenyphosphine, neocuproine (2,9-dimethy1-1,10-phenanthroline), cuproine (2,2'-diquinolyl) and triphenylborane as Lewis acid were prepared. Their electronic spectra are characterized by low-energy electronic transitions which are attributed to phenyl (BPh3) to Lewis base, ligand to ligand charge transfer (LLCT) transitions. These Lewis base-BPh3 complexes display a distinct blue to green fluorescence in solution which originates from the lowest-energy LLCT singlets. (C) 2016 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | MAIN GROUP-METALS; COORDINATION-COMPOUNDS; PHOTOCHEMISTRY; Organoboron complexes; Lewis base-BPh3 adducts; Electronic spectra; LLCT; Fluorescence |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 04 Apr 2019 11:41 |
| Last Modified: | 04 Apr 2019 11:41 |
| URI: | https://pred.uni-regensburg.de/id/eprint/4244 |
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