Chen, Liuping and Luedemann, Hans-Dietrich (2000) Influence of conformational equilibria upon the self-diffusion of the conformers in neat liquids. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 55 (6-7). pp. 605-608. ISSN 0932-0784
Full text not available from this repository. (Request a copy)Abstract
The self-diffusion coefficients D of the isomers of liquid N-isopropyl-N-methylacetamide (IPMAA) and acetylacetone (ACAC) are studied as functions of temperature. For ACAC also pressure dependent studies were undertaken. In IPMAA the cis and trans conformers have almost identical D. In liquid ACAC, D-Keto is always smaller than D-enol, this difference being 15% around 300 K.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PRESSURE; conformers; self diffusion; neat liquids; pressure |
| Subjects: | 500 Science > 570 Life sciences |
| Divisions: | Biology, Preclinical Medicine > Institut für Biophysik und physikalische Biochemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 03 May 2022 08:43 |
| Last Modified: | 03 May 2022 08:43 |
| URI: | https://pred.uni-regensburg.de/id/eprint/42474 |
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