Brunner, Henri and Valerio, C. and Zabel, Manfred (2000) Optically active transition metal complexes. Part 123: new chiral half-sandwich ruthenium complexes, in which the arene ligand is tethered to a PN ligand. NEW JOURNAL OF CHEMISTRY, 24 (5). pp. 275-279. ISSN 1144-0546
Full text not available from this repository. (Request a copy)Abstract
A concept is presented to fix the otherwise labile metal configuration in chiral half-sandwich ruthenium complexes by three-point-attachment ligands. Ligands of this type are prepared by tethering the backbone of the PN ligand 1 to a cyclopentadienyl (2) or arene system (3, 4). In half-sandwich ruthenium complexes the arene-PN ligands bind in a three-point attachment (5, 6) and in a bidentate PN coordination (7-9).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ASYMMETRIC TRANSFER HYDROGENATION; CHLORIDE SUBSTITUTION-REACTIONS; CYCLORUTHENATED (R)(C)-(+)-N,N-DIMETHYL-ALPHA-(2-NAPHTHYL) ETHYLAMINE; SCHIFF-BASE COMPLEXES; X-RAY STRUCTURE; CRYSTAL-STRUCTURES; STEREOCHEMISTRY; ATOM; DIASTEREOSELECTIVITY; ACETOPHENONE; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 May 2022 10:07 |
| Last Modified: | 10 May 2022 10:07 |
| URI: | https://pred.uni-regensburg.de/id/eprint/42542 |
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