Preparation of a sulfated linear (1 -> 4)-beta-D-galactan with variable degrees of sulfation

Vogl, H. and Paper, Dieter H. and Franz, G. (2000) Preparation of a sulfated linear (1 -> 4)-beta-D-galactan with variable degrees of sulfation. CARBOHYDRATE POLYMERS, 41 (2). pp. 185-190. ISSN 0144-8617

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Abstract

A linear 1,4-beta-D-galactan has been prepared by partial acid hydrolysis of the major lupin seed polysaccharide on a preparative scale. The galactan has been characterized by acetylation and methylation analysis, by GPC, as well as by its H-1- and C-13-NMR-spectra. Sulfation with increasing amounts of SO3-pyridine yielded a series of galactan sulfates with increasing DS. In all derivatives, the sulfate groups had a similar pattern of distribution, as shown by methylation analysis. Beside unsulfated parts of the molecule, there were also parts with a multiple substitution pattern. (C) 2000 Elsevier Science Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: URONIC-ACIDS; OLIGOSACCHARIDES
Subjects: 500 Science > 570 Life sciences
600 Technology > 615 Pharmacy
Divisions: Chemistry and Pharmacy > Institute of Pharmacy > Alumni or Retired Professors > Prof. Franz
Depositing User: Dr. Gernot Deinzer
Date Deposited: 25 May 2022 07:46
Last Modified: 25 May 2022 07:46
URI: https://pred.uni-regensburg.de/id/eprint/42841

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