Optically active transition metal complexes, 122. Synthesis of palladium(II) complexes with Schiff base ligands - Intramolecular interactions

Brunner, H and Niemetz, M and Zabel, M (2000) Optically active transition metal complexes, 122. Synthesis of palladium(II) complexes with Schiff base ligands - Intramolecular interactions. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 55 (2). pp. 145-154. ISSN 0932-0776,

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Abstract

Imines of salicylaldehyde and 2,6-diformyl-p-cresol have been used as ligands in palladium(II) complexes. Enantiomerically pure ligands give enantiomerically pure complexes, racemic ligands give racemates and meso-forms. Differences between the respective isomers of the ligands within the complexes and between the diastereomers of the complexes were investigated. Crystal structure analyses established the trans configuration at the metal center.

Item Type: Article
Uncontrolled Keywords: COPPER(II) COMPLEXES; CATALYSTS; Schiff bases; palladium(II) complexes; diastereomers; crystal structure
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner
Depositing User: Dr. Gernot Deinzer
Date Deposited: 20 May 2021 09:37
Last Modified: 20 May 2021 09:37
URI: https://pred.uni-regensburg.de/id/eprint/42882

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