Conductivity of sodium chloride in water+1,4-dioxane mixtures from 5 to 35 degrees C. II. Concentrated solutions

Bešter-Rogač, M. and Neueder, R. and Barthel, J. (2000) Conductivity of sodium chloride in water+1,4-dioxane mixtures from 5 to 35 degrees C. II. Concentrated solutions. JOURNAL OF SOLUTION CHEMISTRY, 29 (1). pp. 51-61. ISSN 0095-9782

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Abstract

Conductivity data of sodium chloride in binary mixtures of water and 1,4-dioxane from 5 to 35 degrees C were measured, covering an electrolyte concentration range up to the limit of solubility in the solvent mixtures and up to 5 mol-dm(-3) in pure water. Data analysis is based on the mean spherical approximation (MSA). Comparison is made with the data representation by the empirical Casteel-Amis equation. The association constants of the MSA are compared with those from chemical model calculations at low concentrations (lcCM).

Item Type: Article
Uncontrolled Keywords: MEAN SPHERICAL APPROXIMATION; ELECTROLYTE-SOLUTIONS; CONDUCTANCE; COEFFICIENTS; MODEL; electrolyte conductivity; concentrated electrolyte solutions; sodium chloride; water-dioxane mixtures
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 31 May 2022 09:09
Last Modified: 31 May 2022 09:09
URI: https://pred.uni-regensburg.de/id/eprint/43019

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