Koenig, Burkhard and Papke, Ulrich and Roedel, Martin (2000) Synthesis of aromatic and heteroaromatic oligoamides on methoxypoly(ethylene glycol) as solubilizing polymer support. NEW JOURNAL OF CHEMISTRY, 24 (1). pp. 39-45. ISSN 1144-0546
Full text not available from this repository.Abstract
A protecting-group-free procedure for the synthesis of short carbo- and heteroaromatic oligoamide chains on MeO-PEG as solubilizing support is introduced. Starting from nitrocarboxylic acids, oligoamides of carboxylic acids derived from N-methylpyrrole, N-methylimidazole and aniline are synthesized that contain up to five arene units. The polymer support facilitates work up procedures and markedly improves the otherwise poor solubility of the products. Each coupling step is monitored by H-1-NMR spectroscopy without cleavage of the product from the polymeric support.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | BASE-PAIR SEQUENCES; MINOR-GROOVE; DNA; RECOGNITION; IMIDAZOLE; POLYAMIDES; NETROPSIN; LIGANDS; MOTIF |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 31 May 2022 09:46 |
| Last Modified: | 31 May 2022 09:46 |
| URI: | https://pred.uni-regensburg.de/id/eprint/43043 |
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