A Second Modification of Beryllium Bromide: beta-BeBr2

Buchner, Magnus R. and Dankert, Fabian and Spang, Nils and Pielnhofer, Florian and von Haenisch, Carsten (2020) A Second Modification of Beryllium Bromide: beta-BeBr2. INORGANIC CHEMISTRY, 59 (23). pp. 16783-16788. ISSN 0020-1669, 1520-510X

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Abstract

The synthesis of a second beryllium bromide modification, beta-BeBr2, was accomplished through recrystallization of alpha-BeBr2 from benzene in the presence of cyclo-decamethylpentasiloxane. This phase was analyzed via single-crystal X-ray diffraction and IR and Raman spectroscopy as well as density functional theory calculations. This enabled a comparison to alpha-BeBr2 and the alpha and beta phases of beryllium chloride and iodide.

Item Type: Article
Uncontrolled Keywords: CRYSTAL-STRUCTURE; COORDINATION; CHEMISTRY; DENSITY; BEF2;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 05 Mar 2021 08:43
Last Modified: 05 Mar 2021 08:43
URI: https://pred.uni-regensburg.de/id/eprint/43162

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