Vogler, Arnd and Bodensteiner, Michael (2020) Synthesis, crystal structure and photoluminescence of a binuclear rhenium(I) carbonyl complex incorporated in a framework of a distorted salophen ligand. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 75 (12). pp. 1061-1064. ISSN 0932-0776, 1865-7117
Full text not available from this repository. (Request a copy)Abstract
Re(CO)(5)Cl reacts with salophenH(2) to yield Re(I)(2)(salophenH)(CO)(6)Cl. A crystal structure determination has shown that this binuclear complex contains two Re(CO)(3) fragments which are bridged by a chloride and a heavily constrained salophenH(-) anion as ligands. Under ambient conditions in solution and in the solid state, the complex displays an orange emission which originates from the lowest-energy IL/MLCT triplet. In solution, this phosphorescence is completely quenched by oxygen.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; carbonyl complex; crystal structure; photo-luminescence; rhenium; salophen |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Central Analytical Services |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 08 Mar 2021 07:04 |
| Last Modified: | 08 Mar 2021 07:04 |
| URI: | https://pred.uni-regensburg.de/id/eprint/43273 |
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