Ziegler, Christoph G. P. and Taube, Clemens and Kelly, John A. and Hierlmeier, Gabriele and Uttendorfer, Maria and Weigand, Jan J. and Wolf, Robert (2020) An unusual Ni2Si2P8 cluster formed by complexation and thermolysis. CHEMICAL COMMUNICATIONS, 56 (90). pp. 14071-14074. ISSN 1359-7345, 1364-548X
Full text not available from this repository. (Request a copy)Abstract
[LSi(eta(2)-P-4)] (L = CH[C(Me)N(Dipp)][C(CH2)N(Dipp)], Dipp = 2,6-diisopropylphenyl) forms well-defined 1 : 1 and 2 : 1 complexes with N-heterocyclic carbene nickel fragments. The cluster compound [(IDipp)Ni2P8(SiL)(2)] (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) is selectively formed by thermolysis of the complex [(IDipp)Ni(mu-eta(2:2)-P-4)SiL].
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSITION-METAL PHOSPHIDES; NICKEL-COMPLEXES; CYCLO-TRIPHOSPHORUS; P-4 ACTIVATION; NANOPARTICLES; CATALYSTS; LIGAND; PHOSPHORUS; NANOSCALE; COBALT; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 08 Mar 2021 07:54 |
| Last Modified: | 08 Mar 2021 07:54 |
| URI: | https://pred.uni-regensburg.de/id/eprint/43339 |
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